Identification

Title

Elemental concentrations in fish from lakes in Northwest England

Abstract

Data comprise concentrations of elements in ashed fish sampled from lakes in the English Lake District in 2012 and 2013. Fish were collected from three lakes (Windermere, Bassenthwaite Lake and Derwent Water) by the Centre for Ecology & Hydrology (CEH) Lake Ecosystems group. Fish species collected were Roach (Rutilus rutilus), Perch (Perca fluviatilis), Ruffe (Gymnocephalus cernuus), Brown trout (Salmo trutta), Pike (Esox lucius) and Vendace (Coregonus albula). All samples were ashed prior to analysis by ICPMS or ICPOES to determine elemental concentrations. Full details about this dataset can be found at https://doi.org/10.5285/ed90df1b-462c-46bb-afbd-59794fb03f6b

Resource type

dataset

Resource locator

https://data-package.ceh.ac.uk/sd/ed90df1b-462c-46bb-afbd-59794fb03f6b.zip

name: Supporting information

description: Supporting information available to assist in re-use of this dataset

function: information

https://data-package.ceh.ac.uk/data/ed90df1b-462c-46bb-afbd-59794fb03f6b

name: Download the data

description: Get a copy of this data

function: download

Unique resource identifier

code

1420712455477

codeSpace

CEH:EIDC:

Dataset language

eng

Spatial reference system

code identifying the spatial reference system

Classification of spatial data and services

Topic category

environment

Keywords

Keyword set

keyword value

Environmental Monitoring Facilities

originating controlled vocabulary

title

reference date

date type

publication

effective date

2008-06-01

Keyword set

keyword value

originating controlled vocabulary

title

reference date

date type

creation

effective date

2012-10-29

Keyword set

keyword value

originating controlled vocabulary

title

reference date

date type

creation

effective date

2006-01-01

Keyword set

keyword value

fish

Roach

Perch

Ruffe

Brown trout

Pike

Vendace

radionuclide

deposition

radiocaesium

radioactive

contamination

Geographic location

West bounding longitude

-8.648

East bounding longitude

1.768

North bounding latitude

60.861

South bounding latitude

49.864

Temporal reference

Temporal extent

Begin position

2012-01-02

End position

Dataset reference date

date type

publication

effective date

2015-03-04

Frequency of update

notPlanned

Quality and validity

Lineage

Fish were collected in 2012 and 2013 from Windermere, Bassenthwaite Lake and Derwent Water in the English Lake District. Species collected were: Roach (Rutilus rutilus), Perch (Perca fluviatilis), Ruffe (Gymnocephalus cernuus), Brown trout (Salmo trutta), Pike (Esox lucius) and Vendace (Coregonus albula). Samples were frozen to minus 20 degrees Centigrade as soon as possible after collection. Fish samples were thoroughly defrosted, weighed and gutted prior to the whole-fish being ashed at 500°C. The ash was then weighed. Ashed fish samples were digested using an aqua regia reagent (fresh 3:1 mixture of concentrated HNO3 and HCl aristar grade) at 175°C for 12 minutes using a microwave oven (CEM, MarsXpress). Analysis of the ashed fish digests was then conducted by ICPMS (Perkin Elmer, NeXION 300D) or ICPOES (Perkin Elmer, 7300 DV). ICPMS measurements were made using two types of instrument operation, either quantitative or semi-quantitative (using Perkin Elmer Total Quant software). The quantitative measurements were made using external calibration after spiking the digests with 10 microgram per litre Ga, In and Re as internal standards to compensate for instrumental drift and matrix effects. The semi-quantitative measurements were made using the ICPMS instrument operating in kinetic energy discrimination (KED) mode with the addition of helium gas. The semi-quantitative and quantitative modes differed as the former used an element concentration to intensity response curve to extrapolate concentrations over a wide mass range. ICPMS and ICPOES instrument limits of detection (LOD) were calculated using mean and standard deviation measurements for the digestion reagent blank (yb, plus sb where yb is blank concentration and sb is three standard deviations of the blank). Method LODs were then calculated taking into account the dilution arising from the digestion procedure. Note that for some elements determined using the semi-quantitative ICPMS method it was not possible to determine instrument LODs from the analysis of a digestion reagent blank and in these cases the instrument LODs were estimated from an assessment of instrument sensitivity and assigned a values of 0.001 microgram per litre (equivalent to a mean method LOD of 0.001 milligrams per kilogram). Results are reported as milligrams per kilogram fresh weight (converted from ash weight using fresh to ash weight ratio for each sample).

Conformity

Conformity report

specification

title

reference date

date type

publication

effective date

2010-12-08

degree

explanation

Data format

name of format

Comma-separated values (CSV)

version of format

Constraints related to access and use

Constraint set

Limitations on public access

Constraint set

Limitations on public access

Constraint set

Limitations on public access

© UK Centre for Ecology & Hydrology

Constraint set

Limitations on public access

If you reuse this data, you should cite: Barnett, C.L., Wells, C., Thacker, S., Guyatt, H.J., Fletcher, J.M., Lawlor, A.J., Winfield, I.J., Beresford, N.A. (2015). Elemental concentrations in fish from lakes in Northwest England. NERC Environmental Information Data Centre https://doi.org/10.5285/ed90df1b-462c-46bb-afbd-59794fb03f6b

Responsible organisations

Responsible party

organisation name

UK Centre for Ecology & Hydrology

email address

enquiries@ceh.ac.uk

responsible party role

pointOfContact

Responsible party

organisation name

Centre for Ecology & Hydrology

email address

enquiries@ceh.ac.uk

responsible party role

author

Responsible party

organisation name

Centre for Ecology & Hydrology

email address

enquiries@ceh.ac.uk

responsible party role

author

Responsible party

organisation name

Centre for Ecology & Hydrology

email address

enquiries@ceh.ac.uk

responsible party role

author

Responsible party

organisation name

Centre for Ecology & Hydrology

email address

enquiries@ceh.ac.uk

responsible party role

author

Responsible party

organisation name

Centre for Ecology & Hydrology

email address

enquiries@ceh.ac.uk

responsible party role

author

Responsible party

organisation name

Centre for Ecology & Hydrology

email address

enquiries@ceh.ac.uk

responsible party role

author

Responsible party

organisation name

Centre for Ecology & Hydrology

email address

enquiries@ceh.ac.uk

responsible party role

author

Responsible party

organisation name

Centre for Ecology & Hydrology

email address

enquiries@ceh.ac.uk

responsible party role

author

Responsible party

organisation name

NERC Environmental Information Data Centre

email address

enquiries@ceh.ac.uk

responsible party role

publisher

Responsible party

organisation name

NERC EDS Environmental Information Data Centre

email address

enquiries@ceh.ac.uk

responsible party role

custodian

Responsible party

organisation name

UK Centre for Ecology & Hydrology

email address

enquiries@ceh.ac.uk

responsible party role

owner

Metadata on metadata

Metadata point of contact

organisation name

Environmental Information Data Centre

full postal address

Lancaster Environment Centre, Library Avenue, Bailrigg

Lancaster

LA1 4AP

UK

email address

info@eidc.ac.uk

responsible party role

pointOfContact

Metadata date

2023-02-09T11:09:19

Metadata language