Identification

Title

Dual stable isotope analysis of nitrogen and oxygen in nitrate in groundwater from Northern Province Chalk in Yorkshire, UK (NERC Grant NE/L002574/1)

Abstract

Dual stable isotope analysis comprising nitrogen-15 and oxygen-18 ratios for groundwater samples collected every 2-3 months over one hydrogeological year from the East Riding of Yorkshire. Isotopic ratios for nitrogen-15, oxygen-18 are both presented as raw and processed to NAIR and VSMOW, respectively. The data are in the form of a Microsoft Excel workbook containing Isotope Ratio Mass Spectrometer runs. The data were collected to understand key sources of nitrate contamination in Chalk groundwater and the dominant processes they undergo, and the extent of any attenuation. The Chalk catchments and the River Terrace Gravel catchment were compared, allowing conclusions to be drawn on the role of nitrate transformation, and the dominant location of transformations, to increase understanding of nitrate dynamics in agricultural systems. Groundwater samples were collected by the University of Leeds, the Environment Agency, Yorkshire Water and South East Water. Nitrate isolation and data interpretation carried out by Josephine McSherry, supervised by L. Jared West and Simon Bottrell. Mass spectrometry was carried out by Rob Newton and Bob Jamieson at the University of Leeds. No isotopic data are absent from the dataset, however oxygen contamination (resulting from the isolation method and since resolved) severely affected run O34b-O. Hydrochemical data relevant to the groundwater samples are not included as they are the property of the Environment Agency, Yorkshire Water or South East Water.

Resource type

nonGeographicDataset

Resource locator

https://webapps.bgs.ac.uk/services/ngdc/accessions/index.html#item171477

name: Data

function: download

https://doi.org/10.5285/aead7506-6523-4b5e-8591-9c895dd03d62

name: Digital Object Identifier (DOI)

function: information

Unique resource identifier

code

http://data.bgs.ac.uk/id/dataHolding/13607888

codeSpace

Dataset language

eng

Spatial reference system

code identifying the spatial reference system

Classification of spatial data and services

Topic category

geoscientificInformation

Keywords

Keyword set

keyword value

originating controlled vocabulary

title

reference date

date type

publication

effective date

2008-06-01

Keyword set

keyword value

Chalk

NGDC Deposited Data

Nitrogen isotopes

Stable isotopes

Nitrates

Groundwater

Oxygen isotopes

originating controlled vocabulary

title

reference date

date type

revision

effective date

2022

Keyword set

keyword value

Keyword set

keyword value

NERC_DDC

Geographic location

West bounding longitude

East bounding longitude

North bounding latitude

South bounding latitude

Temporal reference

Temporal extent

Begin position

2015-11-01

End position

2019-08-31

Dataset reference date

date type

creation

effective date

2022-01-20

Frequency of update

notApplicable

Quality and validity

Lineage

Nitrate was isolated from groundwater samples using the acetone dissolution method developed by Huber et al. 2011. The samples were subjected to pyrolysis at 1450 °C in an Elementar Pyrocube and transferred to an Isoprime continuous flow isotope ratio mass spectrometer (IRMS). The runs include international standards IAEA-NO3 and USGS-34 in addition to several internal laboratory barium nitrate check standards. Carbon-13 ratios are also included as their consistency was monitored.

Conformity

Conformity report

specification

title

reference date

date type

publication

effective date

2011

degree

false

explanation

See the referenced specification

Conformity report

specification

title

reference date

date type

publication

effective date

2010-12-08

degree

false

explanation

See http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2010:323:0011:0102:EN:PDF

Data format

name of format

MS Excel

version of format

Constraints related to access and use

Constraint set

Limitations on public access

Constraint set

Limitations on public access

The copyright of materials derived from the British Geological Survey's work is vested in the Natural Environment Research Council [NERC]. No part of this work may be reproduced or transmitted in any form or by any means, or stored in a retrieval system of any nature, without the prior permission of the copyright holder, via the BGS Intellectual Property Rights Manager. Use by customers of information provided by the BGS, is at the customer's own risk. In view of the disparate sources of information at BGS's disposal, including such material donated to BGS, that BGS accepts in good faith as being accurate, the Natural Environment Research Council (NERC) gives no warranty, expressed or implied, as to the quality or accuracy of the information supplied, or to the information's suitability for any use. NERC/BGS accepts no liability whatever in respect of loss, damage, injury or other occurence however caused.

Responsible organisations

Responsible party

contact position

School of Earth and Environment

organisation name

University of Leeds

full postal address

Leeds

LS2 9JT

email address

not available

responsible party role

principalInvestigator

Responsible party

organisation name

University of Leeds

email address

not available

responsible party role

originator

Responsible party

organisation name

British Geological Survey

email address

not available

responsible party role

distributor

Responsible party

organisation name

British Geological Survey

email address

not available

responsible party role

pointOfContact

Metadata on metadata

Metadata point of contact

organisation name

British Geological Survey

full postal address

Environmental Science Centre,Keyworth

NOTTINGHAM

NG12 5GG

United Kingdom

telephone number

+44 115 936 3100

email address

enquiries@bgs.ac.uk

responsible party role

pointOfContact

Metadata date

2024-04-11

Metadata language