This dataset includes radiocarbon (14C) content and d13C for river water samples collected across the UK. Samples were concentrated to four major catchments - the Ribble, Conwy, Hampshire Avon and Scottish Dee. Samples were collected at high flow. The dataset also includes suspended particulate matter concentration and % organic carbon content. Full details about this dataset can be found at https://doi.org/10.5285/4962468f-54c4-49ff-adb8-03e9e88cffdd